FREE-VOLUME OF SOME POLYMERIC MATERIALS IN LIQUID-EXPANDED MONOLAYER AT THE AIR-WATER-INTERFACE

Authors
CHUNG JJ LEE H SEO BI CHANG SI
Citation
Jj. Chung et al., FREE-VOLUME OF SOME POLYMERIC MATERIALS IN LIQUID-EXPANDED MONOLAYER AT THE AIR-WATER-INTERFACE, Synthetic metals, 71(1-3), 1995, pp. 2011-2012
Citations number
9
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
71
Issue
1-3
Year of publication
1995
Pages
2011 - 2012
Database
ISI
SICI code
0379-6779(1995)71:1-3<2011:FOSPMI>2.0.ZU;2-Z
Abstract
Bidimensional mixtures of polymethylmethacrylate(PMMA), poly-1-trimeth ylsilyl-1-propyne(PTMSP) and poly-1-methyl-2-propylacetylene(PMPA) wit h palmitic acid(PA) were studied in monolayer, in order to compare bet ween molecular areas showed on pi-A isotherms and free volume of each polymer. Increasing degree of negative area deviation from ideality fo r each polymer/PA mixture monolayers were shown in the order of PMMA<P MPA<PTMSP. This result was consistent with the order of gas permeabili ty of these polymer reported.(1,2)