CHARACTERIZATION OF POLY-CUPC SHEET POLYMERS SYNTHESIZED UNDER HIGH-PRESSURE

Authors
YAKUSHI K SHIROTANI I KHAIRULLIN II NAKAZAWA Y KANODA K KOSUGI N TAKEDA S
Citation
K. Yakushi et al., CHARACTERIZATION OF POLY-CUPC SHEET POLYMERS SYNTHESIZED UNDER HIGH-PRESSURE, Synthetic metals, 71(1-3), 1995, pp. 2287-2288
Citations number
5
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
71
Issue
1-3
Year of publication
1995
Pages
2287 - 2288
Database
ISI
SICI code
0379-6779(1995)71:1-3<2287:COPSPS>2.0.ZU;2-7
Abstract
We have characterized the material which has been prepared by the heat treatment of the mixture of 1,2,4,5-tetracyanobenzene (TCNB) and Cu p owder at 5 GPa and 500 degrees C. Dark gray material which incorporate s Cu showed high conductivity (sigma(RT) = 1 Scm(-1)) at room temperat ure. Although the X-ray diffraction and C-13 NMR indicate the inhomoge neous structure, EXAFS and ESR suggest the local structure which is ex pected in the Poly-CuPc sheet polymer.