An ion microprobe with high lateral resolution has been used to study
the chemical reactions at the fibre/matrix interface of metal-matrix c
omposites. During the squeeze-casting process, the Al-Si-Mg matrix rea
cts with the preform made of Saffil fibres (96% Al2O3, 4% SiO2). The r
eaction occurs mainly between the silica binder and Mg from the matrix
according to SiO2 + 2Mg = 2MgO + Si. A continuous layer of MgO was fo
rmed around the fibres, even on surfaces that were not covered by the
silica binder. Possible reasons are discussed for the formation of MgO
in areas where binder coating was missing. In such areas, Mg reduces
SiO2 that is contained in the fibre. However, the fibres (Al2O3) are n
ot attacked by Mg. In the isolated case of fibres that were completely
uncoated, no reaction products were observed at the interface. The pr
esence of silica binder seems to be an essential requirement for this
reaction to occur, When squeeze-casting is performed with sufficiently
high melt temperature, Al from the matrix also reduces silica.