TRIS(3-T-BUTYL-5-METHYLPYRAZOLYL)HYDROBORATO DERIVATIVES OF COPPER AND THALLIUM - THE STRUCTURAL INFLUENCE OF A 5-METHYL SUBSTITUENT

Authors
YOON K PARKIN G
Citation
K. Yoon et G. Parkin, TRIS(3-T-BUTYL-5-METHYLPYRAZOLYL)HYDROBORATO DERIVATIVES OF COPPER AND THALLIUM - THE STRUCTURAL INFLUENCE OF A 5-METHYL SUBSTITUENT, Polyhedron, 14(6), 1995, pp. 811-821
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
6
Year of publication
1995
Pages
811 - 821
Database
ISI
SICI code
0277-5387(1995)14:6<811:TDOCA>2.0.ZU;2-4
Abstract
The molecular structures of the tris(3-t-butyl-5-methylpyrazolyl)hydro borato derivatives of copper and thallium {[Tp(But,Me)]CU}(2), [Tp(But ,Me)]CuCl and Tl[Tp(But,Me)], have been determined by X-ray diffractio n. Comparison of these structures with those of {[Tp(But)]Cu}(2), [Tp( But)]CuCl and Tl[Tp(But)] demonstrates the structural role that alkyl substitution at the remote 5-position of the pyrazolyl group may play in modifying the coordination environment about a metal centre.