AN UNEXPECTED REARRANGEMENT OF THE BICYCLO[2.2.1]-HEPTEN SYSTEM

Authors
CINQUIN C SCHAPER I MANDVILLE G BLOCH R
Citation
C. Cinquin et al., AN UNEXPECTED REARRANGEMENT OF THE BICYCLO[2.2.1]-HEPTEN SYSTEM, Synlett, (4), 1995, pp. 339-340
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
4
Year of publication
1995
Pages
339 - 340
Database
ISI
SICI code
0936-5214(1995):4<339:AUROTB>2.0.ZU;2-P
Abstract
The enzyme catalyzed transesterification of vinylacetate with the meso diol 4 gave the enantiopure corresponding monoacetate 3. The triflate generated from this hydroxy acetate lead to a chiral, non racemic sub stituted furan via a new rearrangement of the bicyclo [2.2.1] skeleton .