CHARACTERIZATION OF THE B(1) (1)PI STATE OF SCANDIUM MONOCHLORIDE

Citation
F. Taher et al., CHARACTERIZATION OF THE B(1) (1)PI STATE OF SCANDIUM MONOCHLORIDE, Journal of physics. B, Atomic molecular and optical physics, 28(6), 1995, pp. 181-183
Citations number
6
Categorie Soggetti
Physics, Atomic, Molecular & Chemical",Optics
ISSN journal
09534075
Volume
28
Issue
6
Year of publication
1995
Pages
181 - 183
Database
ISI
SICI code
0953-4075(1995)28:6<181:COTB(S>2.0.ZU;2-T
Abstract
Laser-induced fluorescent lines in the (3) (II)-I-1 --> B(1) (II)-I-1( 0-0) and (1-1) bands of scandium monochloride are observed spectroscop ically for both isotopomers, (ScCl)-Sc-45-Cl-35 and (ScCl)-Sc-45-Cl-37 . Rotational analysis of the spectra allows the characterization of th e B(1) (II)-I-1 state. Preliminary values of the principal constants a t equilibrium in this state for (SCCl)-S-45-Cl-35 are, in cm(-1): T-e = 6020.3, Delta G(1/2) = 379.1, B-e = 0.1551.