A NEW ONE-DIMENSIONAL FERROMAGNETIC SYSTEM STARTING FROM AN ANTIFERROMAGNETIC TRINUCLEAR CU(II) COMPLEX

Authors
RIBAS J DIAZ C SOLANS X FONTBARDIA M
Citation
J. Ribas et al., A NEW ONE-DIMENSIONAL FERROMAGNETIC SYSTEM STARTING FROM AN ANTIFERROMAGNETIC TRINUCLEAR CU(II) COMPLEX, Inorganica Chimica Acta, 231(1-2), 1995, pp. 229-232
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
231
Issue
1-2
Year of publication
1995
Pages
229 - 232
Database
ISI
SICI code
0020-1693(1995)231:1-2<229:ANOFSS>2.0.ZU;2-O
Abstract
The reaction between an aqueous solution of the trinuclear Cu(II) comp lex {[(tmen)Cu](2)[mu-Cu(pba)]}(ClO4)(2) and NaSCN gives good crystals of a new one-dimensional compound in which one N-thiocyanato ligand i s linked to each terminal Cu(II) ion. One of these thiocyanato ligands is S-coupled to the central Cu(II) atom of another trinuclear entity, giving a pme-dimensional structure with low ferromagnetic behaviour a t low temperature.