OXIDATIVE POLYMERIZATION OF POLY(2-(N-PYRROLYL)ETHYL METHACRYLATE) WITH IRON CHLORIDE

Authors
STANKE D HALLENSLEBEN ML TOPPARE L
Citation
D. Stanke et al., OXIDATIVE POLYMERIZATION OF POLY(2-(N-PYRROLYL)ETHYL METHACRYLATE) WITH IRON CHLORIDE, Synthetic metals, 72(1), 1995, pp. 95-98
Citations number
5
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
72
Issue
1
Year of publication
1995
Pages
95 - 98
Database
ISI
SICI code
0379-6779(1995)72:1<95:OPOPMW>2.0.ZU;2-5
Abstract
Polymers 2 containing pyrrole in the side group were synthesized by ra dical polymerization of 2-(N-pyrrolyl)ethyl methacrylate 1 (PEMA). The PEMA units were coupled by oxidation with iron chloride in nitrometha ne. The polymers reached conductivities about 5X10(-5) S/cm upon dopin g with iodine. The polymers were further characterized using H-1 NMR, IR, gel permeation chromatography and thermogravimetric analysis.