VIBRATIONAL AND STRUCTURAL-ANALYSIS OF A SERIES OF SATURATED ALIPHATIC-COMPOUNDS .10. VIBRATIONAL-SPECTRA OF ADIPIC ACID AND ITS ALKALINE POTASSIUM-SALTS IN AQUEOUS-SOLUTION

Citation
H. Ramsis et al., VIBRATIONAL AND STRUCTURAL-ANALYSIS OF A SERIES OF SATURATED ALIPHATIC-COMPOUNDS .10. VIBRATIONAL-SPECTRA OF ADIPIC ACID AND ITS ALKALINE POTASSIUM-SALTS IN AQUEOUS-SOLUTION, Journal of Raman spectroscopy, 26(4), 1995, pp. 265-272
Citations number
25
Categorie Soggetti
Spectroscopy
ISSN journal
03770486
Volume
26
Issue
4
Year of publication
1995
Pages
265 - 272
Database
ISI
SICI code
0377-0486(1995)26:4<265:VASOAS>2.0.ZU;2-G
Abstract
The infrared and Raman spectra of adipic acid and its potassium salts in aqueous solution were recorded. An assignment of the fundamental vi brations is proposed. The analysis of the polarization of the Raman li nes indicated that the two salts belong to the C-s symmetry group wher eas the acid has C-1 symmetry. In the crystalline state, the acid salt appeared to be of type A according to Speakmann's classification. A c omparison of the conformation was made with that of alkanedioic compou nds and its salts.