The residual stress in microwave plasma-enhanced CVD diamond film was
analyzed using a Raman spectrometer with micrometer spatial resolution
. This enables effective study of isolated crystals grown in the same
deposition run. A variation of the Raman line shape near 1332 cm(-1) w
as observed from different crystals in the same sample. A phenomenolog
ical model was used to describe the shift and splitting of the diamond
Raman line, from which the type and the magnitude of the stress in PE
CVD grown diamond can be assessed. The interrelationship and the origi
n of the stress in the film is discussed.