Sm. Lomakin et Ge. Zaikov, PYROLYSIS AND CARBONIZATION OF CROSS-LINKED POLY(METHYL METHACRYLATE), International journal of polymeric materials, 27(3-4), 1995, pp. 223-230
The thermal degradation of network copolymers of methyl methacrylate w
as studied as a function of the chemical nature of the cross-linking a
gent and the frequency of cross-links. Unlike the linear homopolymer,
both the trimethyllolpropane triacrylate and trimethylolpropane trimet
hacryate networks were found to char when burned. The differences in t
he thermal degradation of these polymers are interpreted in terms of a
simple model for kinetics of polymerization.