ENZYMES IN POLYMER CHEMISTRY .8. CHEMOENZYMATIC SYNTHESIS OF POLYMERIZABLE 11-METHACRYLOYL-AMINOUNDECANOIC ESTER OF 1-O-METHYL-ALPHA-D-GLUCOSE AND 3-O-METHYL-ALPHA-D-GLUCOSE IN 6-O-POSITION

Authors
GEYER U KLEMM D PAVEL K RITTER H
Citation
U. Geyer et al., ENZYMES IN POLYMER CHEMISTRY .8. CHEMOENZYMATIC SYNTHESIS OF POLYMERIZABLE 11-METHACRYLOYL-AMINOUNDECANOIC ESTER OF 1-O-METHYL-ALPHA-D-GLUCOSE AND 3-O-METHYL-ALPHA-D-GLUCOSE IN 6-O-POSITION, Macromolecular rapid communications, 16(4), 1995, pp. 337-341
Citations number
23
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular rapid communications → ACNP
ISSN journal
10221336
Volume
16
Issue
4
Year of publication
1995
Pages
337 - 341
Database
ISI
SICI code
1022-1336(1995)16:4<337:EIPC.C>2.0.ZU;2-9
Abstract
The paper describes the regioselective esterification of a glucopyrano side and glucose derivative with 11-methacryloylaminoundecanoic acid i n the presence of a lipase from Candida antarctica. The obtained modif ied sugar derivatives 6-O-(11-methacryloylaminoundecanoyl)-1-O-methyl- alpha-D-glucopyranoside (3a) and aminoundecanoyl)-3-O-methyl-alpha-D- gluco-pyranose (3b) were polymerized radically with AIBN as initiator.