The blanket system is one of the most important components of a fusion
reactor becuase it has a major impact on both the economics and safet
y of fusion energy. The primary functions of the blanket in a deuteriu
m-tritium-fueled fusion reactor are to convert the fusion energy into
sensible heat and to breed tritium for the fuel cycle. The Blanket Com
parison and Selection Study, conducted earlier, described the overall
comparative performance of various blanket concepts, including liquid
metal, molten salt, water, and helium. This paper discusses the Intern
ational Thermonuclear Experimental Reactor requirements for a self-coo
led blanket that uses liquid Li and for indirectly cooled blankets tha
t use other alkali metals such as NaK. The paper addresses the thermod
ynamics of interactions between the liquid metals (e.g. Li and NaK) an
d structural materials (e.g. V-base alloys), together with associated
corrosion and compatibility issues. Available experimental data are us
ed to assess the long-term performance of the first wall in a liquid m
etal environment. Other key issues include development of electrically
insulating coatings for the first-wall structural material to minimiz
e magnetohydrodynamic (MHD) pressure drop, and tritium permeation and
inventory in self-cooled and indirectly cooled blankets. Acceptable ty
pes of coating (based on their chemical compatibility and physical pro
perties) are identified, and surface modifications to achieve these co
atings on the first wall are discussed. The assessment examines the ex
tent of our knowledge on the performance of structural materials in li
quid metals and identifies needed research and development in several
areas to establish performance envelopes for the first wall in a liqui
d metal environment.