TRANSPORT OF PALLADIUM(II) THROUGH TRIOCTYLAMINE LIQUID MEMBRANE

Authors
FU JS NAKAMURA S AKIBA K
Citation
Js. Fu et al., TRANSPORT OF PALLADIUM(II) THROUGH TRIOCTYLAMINE LIQUID MEMBRANE, Separation science and technology, 30(5), 1995, pp. 793-803
Citations number
12
Categorie Soggetti
Engineering, Chemical","Chemistry Analytical
Journal title
Separation science and technology → ACNP
ISSN journal
01496395
Volume
30
Issue
5
Year of publication
1995
Pages
793 - 803
Database
ISI
SICI code
0149-6395(1995)30:5<793:TOPTTL>2.0.ZU;2-E
Abstract
The permeation behavior of palladium(II) through a supported liquid me mbrane (SLM) impregnated with trioctylamine (TOA) in kerosene has been investigated. By selecting perchloric or nitric acid as a stripping a gent, Pd(II) was transported through the SLM containing 0.5 M TOA and 20% 1-octanol without remaining in the liquid membrane. The permeation rate (k(f,obs)) of Pd(II) for HNO3 was faster than that for HClO4. Pa lladium(II) was concentrated across the SLM from the 0.5 M HCl solutio n into the HClO4 or HNO3 solution.