THE KINETICS OF CYCLIZATION IN THE COURSE OF CONTINUOUS LINEAR POLYCONDENSATION

Authors
IRZHAK TF PEREGUDOV NI IRZHAK VI
Citation
Tf. Irzhak et al., THE KINETICS OF CYCLIZATION IN THE COURSE OF CONTINUOUS LINEAR POLYCONDENSATION, Vysokomolekularnye soedinenia. Seria A, 37(3), 1995, pp. 518-522
Citations number
4
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
37
Issue
3
Year of publication
1995
Pages
518 - 522
Database
ISI
SICI code
0507-5475(1995)37:3<518:TKOCIT>2.0.ZU;2-D
Abstract
The kinetics of formation of the cycles in the process of irreversible linear polycondensation under conditions of continuous supply of fres h initial reactants is studied by numerical solution of the system of kinetic equations. It is shown that the yield and molecular mass distr ibution of the cyclic products vary, depending on the interrelation of supply rate and the kinetic constant of cyclization. The optimum cond itions for the reaction are found.