R. Agnihotry Sa",rashmi,"ramchandran et S. Chandra, PRE-EXISTENCE OF HXWO3 IN E-BEAM DEPOSITED WO3 FILMS, Solar energy materials and solar cells, 36(3), 1995, pp. 289-294
Structural and optical properties of e-beam deposited tungsten trioxid
e (WO3) films in as-deposited and electrochemically coloured states we
re investigated by spectrophotometric and XRD techniques. These invest
igations have shown the as-deposited WO3 films to be porous and with s
mall amount of HxWO3 pre-existing in them. The films further facilitat
e insertion of H+ ions on colouration resulting in tetragonal HxWO3 wi
th a = 4.74 Angstrom and c = 3.19 Angstrom.