LUMINESCENCE LINE NARROWING IN THE LOW-TEMPERATURE GLASSY PHASE OF SOLID C-60

Authors
Citation
R. Bauer et U. Bogner, LUMINESCENCE LINE NARROWING IN THE LOW-TEMPERATURE GLASSY PHASE OF SOLID C-60, Chemical physics letters, 236(3), 1995, pp. 292-298
Citations number
33
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
236
Issue
3
Year of publication
1995
Pages
292 - 298
Database
ISI
SICI code
0009-2614(1995)236:3<292:LLNITL>2.0.ZU;2-A
Abstract
Vibrational zero-phonon lines and structured sidebands are obtained at temperatures below 40 K in C-60 films by narrow-band selective excita tion with a cw Ti:sapphire laser. The large inhomogeneous broadening ( about 130 cm(-1)) of the purely electronic transition (with a maximum at 733 nm) is explained by orientational disorder in the low-temperatu re glassy phase of solid C-60. The peaks in the sidebands can be attri buted to librational modes. The Debye-Waller factor was found to be 0. 3.