ISOTOPIC EXCHANGE KINETICS AND MECHANISMS INVOLVING THE LINEAR COORDINATED NITROSYL GROUP

Authors
ERSHOV AY NIKOLSKII AB
Citation
Ay. Ershov et Ab. Nikolskii, ISOTOPIC EXCHANGE KINETICS AND MECHANISMS INVOLVING THE LINEAR COORDINATED NITROSYL GROUP, Bulletin of the Polish Academy of Sciences. Chemistry, 42(3), 1994, pp. 335-340
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Polish Academy of Sciences. Chemistry → ACNP
ISSN journal
02397285
Volume
42
Issue
3
Year of publication
1994
Pages
335 - 340
Database
ISI
SICI code
0239-7285(1994)42:3<335:IEKAMI>2.0.ZU;2-4
Abstract
The kinetics and mechanisms of nitrogen isotopic exchange between nitr ite ion or nitric oxide and nitrosyl group in six-coordinate transitio n metal complexes comprising linear MNO fragment have been studied. Th e lability of the M-NO linkage in compounds of [MNOX5]q (M = Fe, Ru, X = CN, q = -2; M = Cr, X = CN, q = -3; M = Ru, Os, X = Cl, Br, q = -2; M = Ru, X = NH3, q = +3) has been shown to be dependent upon its stre ngth and electrophilic properties of coordinated NO.