CATALYTIC CU(I) ASSISTED POLYFUNCTIONALIZATION OF ZIRCONACYCLOPENTENES

Authors
LIPSHUTZ BH SEGI M
Citation
Bh. Lipshutz et M. Segi, CATALYTIC CU(I) ASSISTED POLYFUNCTIONALIZATION OF ZIRCONACYCLOPENTENES, Tetrahedron, 51(15), 1995, pp. 4407-4420
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
15
Year of publication
1995
Pages
4407 - 4420
Database
ISI
SICI code
0040-4020(1995)51:15<4407:CCAPOZ>2.0.ZU;2-5
Abstract
Using a catalytic quantity of CuCl . 2LiCl, zirconacyclopentenes can b e regiospecifically transmetallated and subsequently induced to underg o 1,4-additions to enones. Further manipulations of the presumed zirco nium enolates are also presented, including three- and four-component couplings.