1,4-REMOTE STEREOCONTROL VIA ASYMMETRIC [2,3]-WITTIG REARRANGEMENTS

Authors
TOMOOKA K KEONG PH NAKAI T
Citation
K. Tomooka et al., 1,4-REMOTE STEREOCONTROL VIA ASYMMETRIC [2,3]-WITTIG REARRANGEMENTS, Tetrahedron letters, 36(16), 1995, pp. 2789-2792
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
16
Year of publication
1995
Pages
2789 - 2792
Database
ISI
SICI code
0040-4039(1995)36:16<2789:1SVA[R>2.0.ZU;2-3
Abstract
The carbanion rearrangement of the propargylic ether of the beta-(1-al koxyethyl) allyl alcohol was found to proceed with a high degree of ei ther 1,4-syn or 1,4-anti selection by virtue of the proper choice of t he combination of the alkoxy group with the solvent used.