This article summarizes the state of the art of metal preconcentration
and speciation using biological organisms such as algae, plant-derive
d materials, bacteria, yeast, fungi and erythrocytes. Although biosorp
tion has been the subject of increasing research for a variety of reas
ons, including its potential application in the recovery of metals fro
m manufacturing processes, the treatment of contaminated water and the
recovery of precious metals in mining operations, only recently has i
t been exploited for analytical measurement. Basic techniques and prin
ciples are discussed and recent developments reviewed. Special attenti
on is given to immobilization procedures and some biosorption mechanis
ms are considered.