PREPARATION, SPECTROSCOPIC CHARACTERIZATION AND X-RAY STRUCTURE OF CLOHEXYLPHOSPHINYL-N-METHYL(THIOFORMAMIDE)]GOLD(I) CHLORIDE - AU[CY(2)P(O)C(S)N(H)ME]CL

Authors
SIASIOS G TIEKINK ERT
Citation
G. Siasios et Ert. Tiekink, PREPARATION, SPECTROSCOPIC CHARACTERIZATION AND X-RAY STRUCTURE OF CLOHEXYLPHOSPHINYL-N-METHYL(THIOFORMAMIDE)]GOLD(I) CHLORIDE - AU[CY(2)P(O)C(S)N(H)ME]CL, Australian Journal of Chemistry, 48(4), 1995, pp. 757-762
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
48
Issue
4
Year of publication
1995
Pages
757 - 762
Database
ISI
SICI code
0004-9425(1995)48:4<757:PSCAXS>2.0.ZU;2-8
Abstract
The reaction of [AuCl4](-) with Cy(2)P(O)C(S)N(H)Me in the presence of thiodiglycol affords the air-stable adduct Au[Cy(2)P(O)C(S)N(H)Me]Cl which features a linear gold atom geometry defined by a chloride atom and a sulfur atom derived from a monodentate thioformamide ligand. The pale-green crystals are monoclinic, space group P2(1), with unit cell dimensions a 18 . 507(4), b 12 . 204(2), c 18 . 513(6) Angstrom, beta 117 . 69(2)degrees, Z 8; the structure was refined to final R 0 . 042 , 4106 reflections being used.