NEW N,SI,O,C-HETERAPHANES - SYNTHESIS OF A 16-MEMBERED MACROCYCLE

Authors
MARCUS L KLINGEBIEL U NOLTEMEYER M
Citation
L. Marcus et al., NEW N,SI,O,C-HETERAPHANES - SYNTHESIS OF A 16-MEMBERED MACROCYCLE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(4), 1995, pp. 687-690
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
4
Year of publication
1995
Pages
687 - 690
Database
ISI
SICI code
0932-0776(1995)50:4<687:NN-SOA>2.0.ZU;2-S
Abstract
Bis(fluorodiisopropylsilyl) amine [(Me(2)HC)(2)SiF]2NH (1) reacts with the disodium salt of catechole or the disodium salt of resorcinol in a molar ratio 1:1 to give the seven-membered heteraphane [HN(Me(2)HC)( 2)SiO]2C6H4 (2) resp. the 16-membered heteraphane [HN(Me(2)HC)(2)SiOC6 H4OSi(CHMe(2))(2)](2) (3). The chain-like compound [(Me(2)HC)(2)SiFNHS i(CHMe(2))(2)O]2C6H4 (4) is obtained by the reaction of 1 with disodiu m resorcinolate.