D. Braun et C. Hettigrupaner, PHOTOINDUCED POLYMERIZATION .4. GRAFT-COP OLYMERIZATION OF METHYL-METHACRYLATE ONTO POLY(ETHYLENE OXIDE) IN THE PRESENCE OF QUINOLINE DERIVATIVES, Die Angewandte makromolekulare Chemie, 225, 1995, pp. 83-98
When using poly(ethylene oxide) (PEG) as a polymeric hydrogen donator,
grafted polymerization products are obtained upon photoinduced polyme
rization of methyl methacrylate with quinoline derivatives and PEG. Th
e separation of these graft copolymers from the simultaneously formed
homopolymeric poly(methyl methacrylate) (PMMA) and the remainder of no
t converted PEO can be achieved by subsequent extraction with ethyl ac
etate and methanol. With that determination of graft yield, degree of
grafting, grafting success, and grafting height are possible.