Conducting organic polymers may be used for the detection of vapours a
nd gases. A new development is the interrogation of conducting polymer
sensors using high-frequency a.c. measurements. This new gas-sensing
technique needs investigation of the electrical behaviour at high freq
uency (1 MHz-1 GHz) of a number of organic conducting polymers. A sens
or prototype consisting of two straight parallel copper strips on a fi
breglass substrate and a polypyrrole (PPY) layer deposited between the
m is used for this purpose. A mathematical model of this prototype has
been developed using transmission-line theory for modelling its respo
nse over the frequency range 1 MHz-1 GHz. The model permits one to obt
ain the input sensor impedance versus frequency when the PPY complex p
ermittivity (versus frequency, temperature, humidity, gas concentratio
n, etc.) is known, and vice versa.