ON THE REACTIVITY OF N,N-BIS(TRIMETHYL)SILYLATED ENAMINES - MODEL STUDIES ON HETERO-DIELS-ALDER REACTIONS AND OTHER CYCLOADDITIONS

Authors
PAULINI K REISSIG HU RADEMACHER P
Citation
K. Paulini et al., ON THE REACTIVITY OF N,N-BIS(TRIMETHYL)SILYLATED ENAMINES - MODEL STUDIES ON HETERO-DIELS-ALDER REACTIONS AND OTHER CYCLOADDITIONS, Journal fur praktische Chemie, Chemiker-Zeitung, 337(3), 1995, pp. 209-215
Citations number
61
Categorie Soggetti
Chemistry,"Chemistry Applied
Journal title
Journal fur praktische Chemie, Chemiker-Zeitung → ACNP
ISSN journal
09411216
Volume
337
Issue
3
Year of publication
1995
Pages
209 - 215
Database
ISI
SICI code
0941-1216(1995)337:3<209:OTRONE>2.0.ZU;2-0
Abstract
In-situ generated nitroso alkenes underwent smooth hetero Diels-Alder reactions with E-1-[N,N-bis(trimethylsilyl)amino]-1-propene (1) and fu rnished 1,2-oxazines 7-9 in good yields. In contrast, the other n-disi lylated enamines Z-1, 2, and 3 did not react with alpha nitrosostyrene . Thus, a very simple kinetic separation of E/Z-1.