TETRACYANOETHYLENE-HYDROGEN PEROXIDE, A MILD EPOXIDATION SYSTEM OF OLEFINS

Authors
MASAKI Y MIURA T MUKAI I IWATA I ODA H ITOH A
Citation
Y. Masaki et al., TETRACYANOETHYLENE-HYDROGEN PEROXIDE, A MILD EPOXIDATION SYSTEM OF OLEFINS, Chemical and Pharmaceutical Bulletin, 43(4), 1995, pp. 686-688
Citations number
43
Categorie Soggetti
Pharmacology & Pharmacy",Chemistry
Journal title
Chemical and Pharmaceutical Bulletin → ACNP
ISSN journal
00092363
Volume
43
Issue
4
Year of publication
1995
Pages
686 - 688
Database
ISI
SICI code
0009-2363(1995)43:4<686:TPAMES>2.0.ZU;2-U
Abstract
A reagent combination system, tetracyanoethylene-30% hydrogen peroxide , was found to epoxidize olefins efficiently in acetonitrile at room t emperature in a stereospecific manner with retention of the configurat ion of the double bond.