ELECTROCHEMICAL SYNTHESIS OF EXTENDED TTF

Authors
LORCY D CARLIER R ROBERT A TALLEC A LEMAGUERES P OUAHAB L
Citation
D. Lorcy et al., ELECTROCHEMICAL SYNTHESIS OF EXTENDED TTF, Journal of organic chemistry, 60(8), 1995, pp. 2443-2447
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
60
Issue
8
Year of publication
1995
Pages
2443 - 2447
Database
ISI
SICI code
0022-3263(1995)60:8<2443:ESOET>2.0.ZU;2-8
Abstract
An efficient electrochemical synthesis of new extended TTFs (tetrathia fulvalenes) starting from 1,4-dithiafulvenes is presented, and the mec hanism is discussed. Single crystal X-ray structure of the neutral ext ended TTF 7d is reported. These novel pi-electron donor molecules show one two-electron reversible oxidation wave in cyclic voltammetry.