Eucalyptus wood samples were delignified with HCl-catalysed acetic aci
d solutions under selected experimental conditions and treated with Na
ClO solutions. The solid residues obtained were employed as substrates
for enzymatic hydrolysis. The NaClO concentration used in the pretrea
tment step, the liquor/solid ratio and the enzyme/substrate ratio were
considered as operational variables. The experimental data allowed th
e development of generalized kinetic models which provided the necessa
ry information for design calculations. The operational conditions wer
e compared from an engineering viewpoint on the basis of economic esti
mates. Optimum conditions were established from these estimates.