In a study aimed to select a carbon steel for its possible use as a li
ner for a high level radioactive waste canister, galvanic corrosion te
sts of lead/carbon steel galvanic couples in groundwater and in seawat
er were performed at 75 degrees C. Lead behaved anodically due to a cu
rrent polarity inversion phenomenon, and therefore corroded preferenti
ally. This polarity inversion is temperature dependent. Under the same
conditions, commercial lead showed higher corrosion rates in groundwa
ter than high purity lead. No current polarity inversion was detected
in galvanic tests performed either in bentonite suspensions in groundw
ater or in seawater.