RELATIONSHIP BETWEEN SOLID-STATE P-31 NMR PARAMETERS AND X-RAY STRUCTURAL DATA IN SOME ZINC PHOSPHONATES

Authors
MASSIOT D DRUMEL S JANVIER P BUJOLIDOEUFF M BUJOLI B
Citation
D. Massiot et al., RELATIONSHIP BETWEEN SOLID-STATE P-31 NMR PARAMETERS AND X-RAY STRUCTURAL DATA IN SOME ZINC PHOSPHONATES, Chemistry of materials, 9(1), 1997, pp. 6
Citations number
19
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
9
Issue
1
Year of publication
1997
Database
ISI
SICI code
0897-4756(1997)9:1<6:RBSPNP>2.0.ZU;2-O
Abstract
P-31 solid-state NMR spectroscopy is a powerful tool to get structural information about the environment of the phosphorus atoms in zinc pho sphonates. In a series of various known structures taken as reference, the connectivity of the RPO(3) groups (i.e., the number of zinc atoms bonded to each of the three oxygen atoms of the phosphonate units) ca n be differentiated on the basis of the value of the chemical shift as ymmetry and anisotropy.