Bh. Sohn et Re. Cohen, PROCESSIBLE OPTICALLY TRANSPARENT BLOCK-COPOLYMER FILMS CONTAINING SUPERPARAMAGNETIC IRON-OXIDE NANOCLUSTERS, Chemistry of materials, 9(1), 1997, pp. 264-269
Free-standing block copolymer films containing magnetic iron oxide nan
oclusters within the microdomains were produced by static casting. The
thickness of the nanocomposite films was easily controlled to make op
tically transparent thin films. The size distribution of the nanoclust
ers was relatively narrow and the nanoclusters were uniformly distribu
ted within the films. The spherical nanoclusters, ca. 5 nm in diameter
, were identified as gamma-Fe2O3 and had a well-defined crystalline st
ructure. Magnetic measurements revealed that the nanocomposite films a
re superparamagnetic.