SYNTHESES AND PROPERTIES OF SOME NEW TRIS (FLUOROPHENYL)ANTIMONY AND TRIS(FLUOROPHENYL)BISMUTH COMPOUNDS - CRYSTAL-STRUCTURE OF TRIS(2,6-DIFLUOROPHENYL)BISMUTH

Authors
LEWE T NAUMANN D NOWICKI G SCHNEIDER H TYRRA W GILLES T TEBBE KF
Citation
T. Lewe et al., SYNTHESES AND PROPERTIES OF SOME NEW TRIS (FLUOROPHENYL)ANTIMONY AND TRIS(FLUOROPHENYL)BISMUTH COMPOUNDS - CRYSTAL-STRUCTURE OF TRIS(2,6-DIFLUOROPHENYL)BISMUTH, Zeitschrift fur anorganische und allgemeine Chemie, 622(12), 1996, pp. 2009-2015
Citations number
53
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
12
Year of publication
1996
Pages
2009 - 2015
Database
ISI
SICI code
0044-2313(1996)622:12<2009:SAPOSN>2.0.ZU;2-S
Abstract
(2,6-F2C6H3)(3)Bi, (2,4,6-F3C6H2)(3)Bi, and (2,6-F2C6H3)(3)Sb are prep ared via Grignard reactions with BiBr3 and SbBr3, respectively. The sy ntheses and properties of the new compounds and the crystal structure of (2,6-F2C6H3)(3)Bi are described. From the reaction of BiBr3 with Ag (OCOC6H3F2) the bismuth benzoate Bi(OCOC6H3F2)(3) is formed in 83% yie ld. Attempts to prepare (2,6-F2C6H3)(3)Bi by decarboxylation of the bi smuth benzoate failed.