With the aim to enhance interpretation of fragmentation mechanisms dur
ing explosive volcanism from size and shape characteristics of pyrocla
sts experimental studies have been conducted using remelted volcanic r
ock (olivine-melilitite). The melt was fragmented and ejected from a c
rucible by the controlled release of pressurized air volumes (method 1
) or by controlled generation df phreatomagmatic explosions (Molten Fu
el Coolant interaction (MFCI); method 2). Both methods were adjusted s
o that the ejection history of the melt was identical in both cases. T
he experiments demonstrate that exclusively during MFCI, angular parti
cles in the grain size interval 32 to 130 mu m are generated that show
surface textures dominated by cracks and pitting. The physical proces
s of their generation is described as a brittle process acting at cool
ing rates of >10(6) K/s, at stress rates well above 3 GPa/m(2), and du
ring similar to 700 mu s. In this time period the emission of intense
shock waves in the megahertz range was detected, releasing kinetic ene
rgy of >1000 J. By both experimental methods, three more types of part
icles were produced in addition, which could be identified and related
to the acceleration and ejection history of the melt: spherical parti
cles, elongated particles, and Pele's hair. Abundance and grain size d
istribution of these particles were found to be proportional to the ra
te of acceleration and the speed of ejection but were not influenced b
y the experimental method used. Pele's hair occurred at ejection speed
s of >75 m/s.