R. Francesconi et F. Comelli, EXCESS MOLAR ENTHALPIES, DENSITIES, AND EXCESS MOLAR VOLUMES OF DIETHYL CARBONATE IN BINARY-MIXTURES WITH 7 N-ALKANOLS AT 298.15 K, Journal of chemical and engineering data, 42(1), 1997, pp. 45-48
The excess molar enthalpies, H-m(E), and the excess molar volumes, V-m
(E), of diethyl carbonate + seven n-alkanols have been determined at 2
98.15 K and atmospheric pressure in order to investigate interactions
between molecules. Mixtures show an endothermic effect which increases
with the increase of the chain length of alkanols. The same positive
pattern is observed for V-m(E). The experimental results have been cor
related using the Redlich-Kister equation and have been qualitatively
discussed.