AZIRIDINATION OF ALKENES USING 3-ACETOXYAMINOQUINAZOLIN-4-(3H)ONES INTHE PRESENCE OF TERTIARY-AMINES - EVIDENCE FOR AN AZAIMIDE (N-NITRENE) INTERMEDIATE

Authors
ATKINSON RS BARKER E
Citation
Rs. Atkinson et E. Barker, AZIRIDINATION OF ALKENES USING 3-ACETOXYAMINOQUINAZOLIN-4-(3H)ONES INTHE PRESENCE OF TERTIARY-AMINES - EVIDENCE FOR AN AZAIMIDE (N-NITRENE) INTERMEDIATE, Journal of the Chemical Society, Chemical Communications, (8), 1995, pp. 819-820
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1995
Pages
819 - 820
Database
ISI
SICI code
0022-4936(1995):8<819:AOAU3I>2.0.ZU;2-Z
Abstract
Solutions of the triethylammonium imide 8, formed from triethylamine a nd 3-acetoxyaminoquinazolinone 4, react with alkenes at -30 degrees C to give aziridines; the reactivity of the aziridinating intermediate i s consistent with its formulation as an azaimide (N-nitrene).