AZIRIDINO[2',3' 1,6][60]FULLERENE - ISOLATION OF THE FIRST CLOSED [5,6]-BRIDGED FULLERENE ADDUCT/

Authors
BANKS MR CADOGAN JIG GOSNEY I HODGSON PKG LANGRIDGESMITH PRR MILLAR JRA PARKINSON JA RANKIN DWH TAYLOR AT
Citation
Mr. Banks et al., AZIRIDINO[2',3' 1,6][60]FULLERENE - ISOLATION OF THE FIRST CLOSED [5,6]-BRIDGED FULLERENE ADDUCT/, Journal of the Chemical Society, Chemical Communications, (8), 1995, pp. 887-888
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1995
Pages
887 - 888
Database
ISI
SICI code
0022-4936(1995):8<887:A1-IOT>2.0.ZU;2-4
Abstract
In addition to the expected formation of closed [6,6]-bridged aziridin ofullerene 3 by reaction of [60]fullerene with singlet oxycarbonylnitr enes, small amounts (ca. 10%) of previously undetected closed [5,6]-ad ducts 5 have been isolated, and are thought to arise by trapping of tr iplet nitrenes.