W. Henderson et al., IDENTIFICATION OF ZINC AND CADMIUM COMPLEXES OF THE MYCOTOXIN SPORIDESMIN-A BY ELECTROSPRAY MASS-SPECTROMETRY, Journal of the Chemical Society, Chemical Communications, (8), 1995, pp. 889-890
The fungal toxin sporidesmin A (spdA), responsible for the occurrence
of facial eczema in livestock, forms a dianionic thiolato complex of t
he type [(spdA)(2)M](2-) with zinc and cadmium, identified by electros
pray mass spectrometry; such complexes may be important in the protect
ion against facial eczema offered by zinc salts.