A NEW METHOD FOR THE SYNTHESIS OF NITRONES AND THEIR CONVERSION TO 3,5-DIARYLISOXAZOLINES

Citation
B. Balasundaram et al., A NEW METHOD FOR THE SYNTHESIS OF NITRONES AND THEIR CONVERSION TO 3,5-DIARYLISOXAZOLINES, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 34(5), 1995, pp. 367-371
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03764699
Volume
34
Issue
5
Year of publication
1995
Pages
367 - 371
Database
ISI
SICI code
0376-4699(1995)34:5<367:ANMFTS>2.0.ZU;2-R
Abstract
droxybenzyl-N-hydroxylamine)-1,3-diarylpropen-l-ol (1) on treatment wi th hydroxylamine hydrochloride, sodium acetate and acetone gives hydro xyimino-N-(1'-methylethylidene)-1-propylamine N-oxide (2). The structu re of 2 has been confirmed by X-ray analysis. The nitrones (2) have be en converted into 3,5-diarylisoxazolines (3) in good yields in the pre sence of polyphosphoric acid.