SELECTIVE ENZYMATIC-HYDROLYSIS OF (Z,E)-DIMETHYL-2,4-HEXADIENEDIOATE - PREPARATION OF (Z,E)-DIFUNCTIONALIZED DIENES

Authors
MARTIN ME PLANCHENAULT D HUET F
Citation
Me. Martin et al., SELECTIVE ENZYMATIC-HYDROLYSIS OF (Z,E)-DIMETHYL-2,4-HEXADIENEDIOATE - PREPARATION OF (Z,E)-DIFUNCTIONALIZED DIENES, Tetrahedron, 51(17), 1995, pp. 4985-4990
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
17
Year of publication
1995
Pages
4985 - 4990
Database
ISI
SICI code
0040-4020(1995)51:17<4985:SEO(->2.0.ZU;2-M
Abstract
Enzymatic hydrolysis of (Z,E)-dimethyl-2,4-hexadienedioate 6 by Pig Li ver Esterase mainly led to (2E,4Z)-5-methoxycarbonyl-2,4-pentadienoic acid 2a. This compound was a starting material for the preparation of other difunctionalized dienes.