Mi. Toral et P. Richter, SIMULTANEOUS DETERMINATION OF COPPER AND IRON BY SOLVENT-EXTRACTION AND FIRST DERIVATIVE SPECTROPHOTOMETRY, Analytical letters, 28(6), 1995, pp. 1083-1094
A simple, sensitive and selective first derivative spectrophotometric
method has been developed for the determination of copper and iron in
mixtures. The method is based on the recovery of the analytes, by liqu
id-liquid extraction, integrated reaction with 5-phenyl-3-(4-phenyl-2-
pyridinyl)-1,2,4-triazine (PPT) and perchlorate in dichloroethane and
on the subsequent direct derivative spectrophotometric measurement usi
ng the zero-crossing approach for determination of both analytes. Copp
er and Iron were thus determined in the ranges 50-2500 ng/ml and 2-120
ng/ml, respectively, in the presence of one another. The detection li
mits achieved (3 sigma) were found to be 17 ng/ml of copper and 0.7 ng
/ml of iron. The relative standard deviations were in all instances le
ss than 3.1%. The proposed method was applied to the determination of
both analytes in well water and the results were consistent with those
provided by the AAS standard method.