SYNTHESIS OF ELECTRIC CONDUCTIVE POLY(ARYLENE VINYLENE) CONTAINING VINYL PYRROLE (PVP)

Authors
KIM DY HA CS CHO WJ
Citation
Dy. Kim et al., SYNTHESIS OF ELECTRIC CONDUCTIVE POLY(ARYLENE VINYLENE) CONTAINING VINYL PYRROLE (PVP), Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 247, 1994, pp. 1-10
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
247
Year of publication
1994
Pages
1 - 10
Database
ISI
SICI code
1058-725X(1994)247:<1:SOECPV>2.0.ZU;2-K
Abstract
A new polyarylenevinylene containing vinyl pyrrole (PVP) was obtained from the monomer, 2,5-bis (methylenedimethylsulfonium) chloride pyrrol e, which was prepared from 2,5-dimethylpyrrole by the modified sulfoni um polyelectrolyte precursor route. The polymerization conditions for the preparation of precursor polymers are described. The highest yield was obtained when the PVP was synthesized at -40 degrees C with the m onomer/base concentration ratios of 0.5/0.2 and thermally eliminated a t 220 degrees C. The electrical conductivity of the PVP synthesized wi th aforementioned conditions was given as 6.8 x 10(-7) Scm(-1).