ENZYMATIC-SYNTHESIS OF BETA-N-ACETYLHEXOSAMINIDES OF ERGOT ALKALOIDS
Citation
V. Kren et al., ENZYMATIC-SYNTHESIS OF BETA-N-ACETYLHEXOSAMINIDES OF ERGOT ALKALOIDS, Biocatalysis, 10(1-4), 1994, pp. 181-193
Categorie Soggetti
Biology,"Biothechnology & Applied Migrobiology
SICI code
0886-4454(1994)10:1-4<181:EOBOEA>2.0.ZU;2-K
Abstract
2-Acetamido-2-deoxy-O-beta-D-galactopyranosides and 2-acetamido-2-deox
y-O-beta-D-glucopyranosides of the representatives of the three classe
s of the ergot alkaloids, i.e., elymoclavine (1a) (clavines), chanocla
vine (2a) (secoclavines) and ergometrine (3a)/ergometrinine (4a) (lyse
rgic/iso-lysergic acid derivatives) were prepared via transglycosylati
on catalysed by beta-N-acetylhexosaminidase from Aspergillus oryzae.