AN INSIGHT INTO THE ACTIVE-SITE OF PSEUDOMONAS-FLUORESCENS (P-CEPACIA) LIPASE TO DEFINE THE STEREOCHEMICAL DEMAND FOR THE TRANSESTERIFICATION IN ORGANIC-SOLVENTS

Authors
FERRABOSCHI P CASATI S DEGRANDI S GRISENTI P SANTANIELLO E
Citation
P. Ferraboschi et al., AN INSIGHT INTO THE ACTIVE-SITE OF PSEUDOMONAS-FLUORESCENS (P-CEPACIA) LIPASE TO DEFINE THE STEREOCHEMICAL DEMAND FOR THE TRANSESTERIFICATION IN ORGANIC-SOLVENTS, Biocatalysis, 10(1-4), 1994, pp. 279-288
Citations number
30
Categorie Soggetti
Biology,"Biothechnology & Applied Migrobiology
Journal title
Biocatalysis → ACNP
ISSN journal
08864454
Volume
10
Issue
1-4
Year of publication
1994
Pages
279 - 288
Database
ISI
SICI code
0886-4454(1994)10:1-4<279:AIITAO>2.0.ZU;2-D
Abstract
The Pseudomonas fluorescens lipase-catalyzed transesterification of 2- methyl alkanols 1 and the 2-substituted oxiranemethanols 2 with vinyl acetate in organic solvents has been studied and the results discussed in terms of steric and electronic demand within the recently postulat ed models of the lipase active site.