The nonlinear transmission of tetrabenzporphyrin dissolved in tetrahyd
rofuran was measured with the Z-scan technique at 532 nm with nanoseco
nd pulses. The excited-state absorption cross section, the excited-sta
te refractive-index cross section, and the linear and nonlinear absorp
tion contributing to a thermal index change have been determined. To o
ur knowledge, the excited-state cross section and its effective ratio
to the ground-state cross section are the largest values reported to d
ate.