SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE [NB(O)(S-2)(2)SH](2-), [NB(S)(3)SH](2-), AND ([NB(S)(3)]O-2)(4-) ANIONS - NEW ELEMENTARY THIONIOBATES AND OXOTHIONIOBATES

Authors
MANDIMUTSIRA BS CHEN SJ DEMADIS KD COUCOUVANIS D
Citation
Bs. Mandimutsira et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE [NB(O)(S-2)(2)SH](2-), [NB(S)(3)SH](2-), AND ([NB(S)(3)]O-2)(4-) ANIONS - NEW ELEMENTARY THIONIOBATES AND OXOTHIONIOBATES, Inorganic chemistry, 34(9), 1995, pp. 2267-2268
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
9
Year of publication
1995
Pages
2267 - 2268
Database
ISI
SICI code
0020-1669(1995)34:9<2267:SASCOT>2.0.ZU;2-N
Abstract
The synthesis and structural characterization of three new elementary chalcogenometallates is reported. The [(O)Nb(S-2)(2)(SH)](2-) and {[Nb (S)(3)](2)(mu-O)}(4-) anions have been obtained in the reactions of th e [Nb(S)(3)(S(t)Bu)](2-) anion with elemental sulfur and Et(3)N respec tively in the presence of water. The [(O)Nb(S-2)(2)(SB)](2-) anion rea cts with Et(3)P to give the [Nb(S)(3)(SH)](2-) anion. [GRAPHICS]