THE TRIFLUOROACETIC ANHYDRIDE-SODIUM IODIDE SYSTEM AS A REAGENT FOR DETERMINATION AND MICRODETERMINATION OF NITROXIDE RADICALS

Authors
CIESIELSKI W KUDZIN ZH GRABOWSKI G
Citation
W. Ciesielski et al., THE TRIFLUOROACETIC ANHYDRIDE-SODIUM IODIDE SYSTEM AS A REAGENT FOR DETERMINATION AND MICRODETERMINATION OF NITROXIDE RADICALS, Talanta, 42(4), 1995, pp. 519-526
Citations number
19
Journal title
Talanta
ISSN journal
00399140 → ACNP
Volume
42
Issue
4
Year of publication
1995
Pages
519 - 526
Database
ISI
SICI code
0039-9140(1995)42:4<519:TTAISA>2.0.ZU;2-3
Abstract
A trifluoroacetic anhydride-sodium iodide mixture (TFAA-I) reacts with nitroxide radicals with liberation of iodine. Since stoichiometric am ounts of iodine are formed from nitroxides, the TFAA-I reagent can be applied to their analytical determination. Two procedures for the dete rmination of nitroxides (titrimetric on mu mol and spectrometric on nm ol levels) are described.