Although it is still widely assumed that H-1 magnetic resonance imagin
g of large samples is limited to relatively mobile liquid-like materia
ls, recent implementation of a method known as Single Point Imaging (S
PI) allows one to directly image rigid solids over sample sire ranges
that make the method potentially very valuable for routine application
to numerous industrially relevant problems. In this preliminary summa
ry we dwell in detail on the experimental advantages and limitations o
f the technique to put its capabilities in perspective. Applications t
o a diverse selection of semicrystalline solids are presented to illus
trate the potential of the method for the characterization of polymers
and food products.