The surface quality of bare substrates and preparation procedures take
on an important role in optical coating performances. The most common
ly used techniques of characterization generally give information abou
t roughness and local defects. A photothermal deflection technique is
used for mapping surface absorption of fused-silica and glass substrat
es. We show that absorption mapping gives specific information on surf
ace contamination of bare substrates. We present experimental results
concerning substrates prepared by different cleaning and polishing tec
hniques. We show that highly polished surfaces lead to the lowest valu
es of residual surface absorption. Moreover the cleaning behavior of s
urfaces of multicomponent glasses and their optical performance in ter
ms of absorption are proved to be different from those of fused silica
.