Using the best available relations describing the thermodynamic behavi
our of H2O (steam), numerous shock wave states realized on isentropic
expansions starting at various initial points, were computed. The resu
lts obtained were approximated by explicit relations having mathematic
al forms similar to those of the ideal gas shock wave but with differe
nt coefficients and exponents such as to describe the real gas steam.
The numerous values of these new coefficients and exponents correspond
ing to the stagnation points were fitted by appropriate curves and are
illustrated in diagrams with respect to the stagnation temperature an
d the stagnation density as a parameter.